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The mixture second virial coefficient B is a function of temperature and composition Its exact composition dependence is given by statistical mechanics, and this makes the virial equation preeminent among equations of state where it is applicable, ie, to gases at low to moderate pressures The equation giving this composition dependence is:

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where y represents mole fractions in a gas mixture The indices i and j identify species, and both run over all species present in the mixture The virial coefficient Bij characterizes a bimolecular interaction between molecule i and molecule j , and therefore Bij = B j i The summations account for all possible bimolecular interactions For a binary mixture i = l , 2 and j = l , 2 ; the expansion of Eq (1157) then gives:

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you give vi the cold shoulder, take a moment to get comfortable with it In difficult situations, you may not have a pretty graphical editor at your disposal, and vi is ubiquitous across all UNIX systems The version of vi that ships with Linux distributions is vim (VI iMproved) It has a lot of what made vi popular in the first place and many features that make it useful in today s typical environments (including a graphical interface if the X Window System is running) To start vi, simply type

Two types of virial coefficients have appeared: Bll and B22,for which the successive subscripts are the same, and B I 2 ,for which the two subscripts are different The first type is a purespecies virial coefficient; the second is a mixture property, known as a cross coeficient Both are functions of temperature only Expressions such as Eqs (1157) and (1158) relate mixture coefficients to pure-species and cross coefficients They are called mixing rules Equation ( 1158) allows derivation of expressions for In $1 and In $2 for a binary gas mixture that obeys Eq (337) Written for n mol of gas mixture, it becomes:

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Differentiation with respect to nl gives:

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in Eq (1156) yields:

It has been argued that emacs is an operating system all by itself It s big, featurerich, expandable, programmable, and all-around amazing If you re coming from a GUI background, you ll probably find emacs a pleasant environment to work with at first On its face, it works like Notepad in terms of its interface Yet underneath is a complete interface to the GNU development environment, a mail reader, a news reader, a web browser, and even a psychiatrist (well, not exactly) To start emacs, simply type

where the integration is elementary, because B is not a function of pressure All that remains is evaluation of the derivative Equation (1158) for the second virial coefficient may be written:

OK, now it s time to take a look at the VARIABLE block. This block is found on the Complete Palette on the Data fly-out menu. Select the VARIABLE block, and drop it on the beam (see Figure 18-1).

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where Since yi = n i / n ,

Differentiation gives:

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Therefore, Similarly,

5:

+ ~22812)

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