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Preceding chapters have dealt largely with pure substances or with constant-composition mixtures eg, air However, composition changes are the desired outcome, not only of chemical reactions, but of a number of industrially important mass-transfer operations Thus composition becomes a primary variable in the remaining chapters of this text Processes such as distillation, absorption, and extraction bring phases of different composition into contact, and when the phases are not in equilibrium, mass transfer between the phases alters their compositions Both the extent of change and the rate of transfer depend on the departure of the system from equilibrium Thus, for quantitative treatment of mass transfer the equilibrium T, P, and phase compositions must be known The most commonly encountered coexisting phases in industrial practice are vapor and liquid, although liquidlliquid, vaporlsolid, and liquidlsolid systems are also found In this chapter we first discuss the nature of equilibrium, and then consider two rules that give the number of independent variables required to determine equilibrium states There follows in Sec 103 a qualitative discussion of vaporAiquid phase behavior In Sec 104 we introduce the two simplest formulations that allow calculation of temperatures, pressures, and phase compositions for systems in vaporlliquid equilibrium The first, known as Raoult's law, is valid only for systems at low to moderate pressures and in general only for systems comprised of chemically similar species The second, known as Henry's law, is valid for any species present at low concentration, but as presented here is also limited to systems at low to moderate pressures A modification of Raoult's law that removes the restriction to chemically similar species is treated in Sec 105 Finally in Sec 106 calculations based on equilibrium ratios or K-values are considered The treatment of vaporAiquid equilibrium is developed further in Chaps 12 and 14

Running su without any parameters will automatically try to make you the root user You ll be prompted for the root password and, if you enter it correctly, will drop down to a root shell If you are already the root user and want to switch to another ID, you don t need to enter the new password when you use this command For example, if you re logged in as the user yyang and want to switch to the root user, type this command:

Equilibrium is a static condition in which no changes occur in the macroscopic properties of a system with time This implies a balance of all potentials that may cause change In engineering practice, the assumption of equilibrium is justified when it leads to results of satisfactory accuracy For example, in the reboiler for a distillation column, equilibrium between vapor and

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You will be prompted for root s password If you re logged in as root and want to switch to, say, user yyang, enter this command:

liquid phases is commonly assumed For finite vaporization rates this is an approximation, but it does not introduce significant error into engineering calculations An isolated system consisting of liquid and vapor phases in intimate contact eventually reaches a final state wherein no tendency exists for change to occur within the system The temperature, pressure, and phase compositions reach final values which thereafter remain fixed The system is in equilibrium Nevertheless, at the microscopic level, conditions are not static The molecules comprising a phase at a given instant are not the same molecules that later occupy the same phase Molecules with sufficiently high velocities near the interface overcome surface forces and pass into the other phase However, the average rate of passage of molecules is the same in both directions, and no net interphase transfer of material occurs

You will not be prompted for yyang s password The optional hyphen (-) parameter tells su to switch identities and run the login scripts for that user For example, if you re logged in as root and want to switch over to user yyang with all of his login and shell configurations, type this command:

In addition, from Eq (1 152),

Logic values only have two choices: True or False An NXT-G VARIABLE block configured to hold a logical value can hold only True or False and nothing else..

TIP The sudo command is used extensively (instead of su) on Debian-based distributions such as Ubuntu to execute commands as another user When configured properly, sudo offers finer grained controls than su does

Values of )i for species i in solution are readily found from equations of state The simplest form of the virial equation provides a useful example Written for a gas mixture it is exactly the same as for a pure species:

Editors are easily among the bulkiest of common tools, but they are also the most useful Without them, making any kind of change to a text file would be a tremendous undertaking Regardless of your Linux distribution, you will have gotten a few editors You should take a few moments to get comfortable with them NOTE Not all distributions come with all of the editors listed here

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